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Faculty of Biology, Chemistry & Earth Sciences

Inorganic Chemistry II – Catalyst Design – Professor Dr. Rhett Kempe

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Selected Publications

year    2018   2017   2016   2015   2014    all years

2018

Kempe, Rhett; Zhang, Guoying; Irrgang, Torsten; Dietel, Thomas; Kallmeier, Fabian
Manganese‐catalyzed Dehydrogenative Alkylation or α‐Olefination of Alkyl‐N‐Heteroaromatics by Alcohols
in Angewandte Chemie International Edition vol. 57 (2018) issue 29. - pp. 9131-9135
doi:10.1002/anie.201801573 ...

Forberg, Daniel; Schwob, Tobias; Kempe, Rhett
Catalytic condensation for the formation of polycyclic heteroaromatic compounds
in Nature Communications vol. 9 (2018)
doi:10.1038/s41467-018-04143-6 ...

Kallmeier, Fabian; Kempe, Rhett
Manganese Complexes for (De)Hydrogenation Catalysis: A Comparison to Cobalt and Iron Catalysts
in Angewandte Chemie International Edition vol. 57 (2018) issue 1. - pp. 46-60
doi:10.1002/anie.201709010 ...

2017

Gollwitzer, Andreas; Dietel, Thomas; Kretschmer, Winfried P.; Kempe, Rhett
A Broadly Tunable Synthesis of Linear α-Olefins
in Nature Communications vol. 8 (2017)
doi:10.1038/s41467-017-01507-2 ...

Kallmeier, Fabian; Dudziec, Beata; Irrgang, Torsten; Kempe, Rhett
Manganese-Catalyzed Sustainable Synthesis of Pyrroles from Alcohols and Amino Alcohols
in Angewandte Chemie International Edition vol. 56 (2017) issue 25. - pp. 7261-7265
doi:10.1002/anie.201702543 ...

Deibl, Nicklas; Kempe, Rhett
Manganese-Catalyzed Multicomponent Synthesis of Pyrimidines from Alcohols and Amidines
in Angewandte Chemie International Edition vol. 56 (2017) issue 6. - pp. 1663-1666
doi:10.1002/anie.201611318 ...

Hille, Toni; Irrgang, Torsten; Kempe, Rhett
The Synthesis of meta-Functionalized Pyridines via Selective Dehydrogenative Heterocondensation of β- and γ-Amino Alcohols
in Angewandte Chemie International Edition vol. 56 (2017) issue 1. - pp. 371-374
doi:10.1002/anie.201610071 ...

2016

Schwob, Tobias; Kempe, Rhett
A Reusable Co Catalyst for the Selective Hydrogenation of Functionalized Nitroarenes and the Direct Synthesis of Imines and Benzimidazoles from Nitroarenes and Aldehydes
in Angewandte Chemie International Edition vol. 55 (2016) issue 48. - pp. 15175-15179
doi:10.1002/anie.201608321 ...

Forberg, Daniel; Schwob, Tobias; Zaheer, Muhammad; Friedrich, Martin; Miyajima, Nobuyoshi; Kempe, Rhett
Single-catalyst high-weight% hydrogen storage in an N-heterocycle synthesized from lignin hydrogenolysis products and ammonia
in Nature Communications vol. 7 (2016)
doi:10.1038/ncomms13201 ...

Kallmeier, Fabian; Irrgang, Torsten; Dietel, Thomas; Kempe, Rhett
Highly Active and Selective Manganese C=O Bond Hydrogenation Catalysts : The Importance of the Multidentate Ligand, the Ancillary Ligands, and the Oxidation State
in Angewandte Chemie International Edition vol. 55 (2016) issue 39. - pp. 11806-11809
doi:10.1002/anie.201606218 ...

Deibl, Nicklas; Kempe, Rhett
General and Mild Cobalt-Catalyzed C-Alkylation of Unactivated Amides and Esters with Alcohols
in Journal of the American Chemical Society vol. 138 (2016) issue 34. - pp. 10786-10789
doi:10.1021/jacs.6b06448 ...

2015

Rösler, Sina; Ertl, Michael; Irrgang, Torsten; Kempe, Rhett
Cobalt-Catalyzed Alkylation of Aromatic Amines by Alcohols
in Angewandte Chemie International Edition vol. 54 (2015) issue 50. - pp. 15046-15050
doi:10.1002/anie.201507955 ...

Ewert, Julia-Katharina; Weingarth, Daniel; Denner, Christine; Friedrich, Martin; Zeiger, M.; Schreiber, Anna; Jäckel, Nicolas; Presser, Volker; Kempe, Rhett
Enhanced capacitance of nitrogen-doped hierarchically porous carbide-derived carbon in matched ionic liquids
in Journal of Materials Chemistry A vol. 3 (2015) issue 37. - pp. 18906-18912
doi:10.1039/C5TA04773K ...

Zaheer, Muhammad; Kempe, Rhett
Catalytic Hydrogenolysis of Aryl Ethers : A Key Step in Lignin Valorization to Valuable Chemicals
in ACS Catalysis vol. 5 (2015) issue 3. - pp. 1675-1684
doi:10.1021/cs501498f ...

Deibl, Nicklas; Ament, Kevin; Kempe, Rhett
A Sustainable Multicomponent Pyrimidine Synthesis
in Journal of the American Chemical Society vol. 137 (2015) issue 40. - pp. 12804-12807
doi:10.1021/jacs.5b09510 ...

Rösler, Sina; Obenauf, Johannes; Kempe, Rhett
A Highly Active and Easily Accessible Cobalt Catalyst for Selective Hydrogenation of C═O Bonds
in Journal of the American Chemical Society vol. 137 (2015) issue 25. - pp. 7998-8001
doi:10.1021/jacs.5b04349 ...

2014

Noor, Awal; Qayyum, Sadaf; Bauer, Tobias; Schwarz, Stefan; Weber, Birgit; Kempe, Rhett
CO₂ and SO₂ activation by a Cr–Cr quintuple bond
in Chemical Communications vol. 50 (2014) issue 86. - pp. 13127-13130
doi:10.1039/C4CC05071A ...

Hille, Toni; Irrgang, Torsten; Kempe, Rhett
The synthesis of benzimidazoles and quinoxalines from aromatic diamines and alcohols by iridium-catalyzed acceptorless dehydrogenative alkylation
in Chemistry : a European Journal vol. 20 (2014) issue 19. - pp. 5569-5572
doi:10.1002/chem.201400400 ...

Butovskii, Mikhail V.; Oelkers, Benjamin; Bauer, Tobias; Bakker, Jacinta M.; Bezugly, Viktor; Wagner, Frank R.; Kempe, Rhett
Lanthanoid-transition-metal bonding in bismetallocenes
in Chemistry : a European Journal vol. 20 (2014) issue 10. - pp. 2804-2811
doi:10.1002/chem.201304125 ...

Forberg, Daniel; Obenauf, Johannes; Friedrich, Martin; Hühne, Sven-Martin; Kempe, Rhett; Mader, Werner; Motz, Günter
The synthesis of pyrroles via acceptorless dehydrogenative condensation of secondary alcohols and 1,2-amino alcohols mediated by a robust and reusable catalyst based on nanometer-sized iridium particles
in Catalysis Science & Technology vol. 4 (2014) issue 12. - pp. 4188-4192
doi:10.1039/C4CY01018C ...

Ruch, Susanne; Irrgang, Torsten; Kempe, Rhett
New iridium catalysts for the selective alkylation of amines by alcohols under mild conditions and for the synthesis of quinolines by acceptor-less dehydrogenative condensation
in Chemistry : a European Journal vol. 20 (2014) issue 41. - pp. 13279-13285
doi:10.1002/chem.201402952 ...

2013

Haas, Isabelle; Dietel, Thomas; Press, Konstantin; Kol, Moshe; Kempe, Rhett
Aminopyridinate-FI Hybrids, Their Hafnium and Titanium Complexes, and Their Application in the Living Polymerization of 1-Hexene
in Chemistry : a European Journal vol. 19 (2013) issue 42. - pp. 14254-14262
doi:10.1002/chem.201301511 ...

Hermannsdörfer, Justus; Friedrich, Martin; Kempe, Rhett
Colloidal Size Effect and Metal-Particle Migration in M@MOF/PCP Catalysis
in Chemistry : a European Journal vol. 19 (2013) issue 41. - pp. 13652-13657
doi:10.1002/chem.201302809 ...

Haas, Isabelle; Hübner, Christian G.; Kretschmer, Winfried P.; Kempe, Rhett
A Highly Efficient Titanium Catalyst for the Synthesis of Ultrahigh-Molecular-Weight Polyethylene (UHMWPE)
in Chemistry : a European Journal vol. 19 (2013) issue 28. - pp. 9132-9136
doi:10.1002/chem.201301176 ...

Bauer, Tobias; Wagner, Frank R.; Kempe, Rhett
Ternary Rare-Earth Transition-Metal Polyhydride Cluster Compounds
in Chemistry : a European Journal vol. 19 (2013) issue 27. - pp. 8732-8735
doi:10.1002/chem.201301290 ...

Michlik, Stefan; Kempe, Rhett
Regioselectively functionalized pyridines from sustainable resources
in Angewandte Chemie International Edition vol. 52 (2013) issue 24. - pp. 6326-6329
doi:10.1002/anie.201301919 ...

Michlik, Stefan; Kempe, Rhett
A sustainable catalytic pyrrole synthesis
in Nature Chemistry vol. 5 (2013) issue 2. - pp. 140-144
doi:10.1038/nchem.1547 ...

Noor, Awal; Bauer, Tobias; Todorova, Tanya K.; Weber, Birgit; Gagliardi, Laura; Kempe, Rhett
The Ligand-Based Quintuple Bond-Shortening Concept and Some of Its Limitations
in Chemistry : a European Journal vol. 19 (2013) issue 30. - pp. 9825-9832
doi:10.1002/chem.201301240 ...

2012

Pillai, Saravana K. T.; Kretschmer, Winfried P.; Denner, Christine; Motz, Günter; Hund, Markus; Fery, Andreas; Trebbin, Martin; Förster, Stephan; Kempe, Rhett
SiCN Nanofibers with a Diameter Below 100 nm Synthesized via Concerted Block Copolymer Formation, Microphase Separation, and Crosslinking
in Small vol. 9 (2012) issue 7. - pp. 984-989
doi:10.1002/smll.201202121 ...

Pillai, Saravana K. T.; Kretschmer, Winfried P.; Trebbin, Martin; Förster, Stephan; Kempe, Rhett
Tailored Nanostructuring of End-Group-Functionalized High-Density Polyethylene Synthesized by an Efficient Catalytic Version of Ziegler’s "Aufbaureaktion"
in Chemistry : a European Journal vol. 18 (2012) issue 44. - pp. 13974-13978
doi:10.1002/chem.201202506 ...

Hermannsdörfer, Justus; Friedrich, Martin; Miyajima, Nobuyoshi; Albuquerque, Rodrigo Q.; Kümmel, Stephan; Kempe, Rhett
Ni/Pd@MIL-101: synergistic catalysis with cavity-conform Ni/Pd nanoparticles
in Angewandte Chemie International Edition vol. 51 (2012) issue 46. - pp. 11473-11477
doi:10.1002/anie.201205078 ...

Oelkers, Benjamin; Butovskii, Mikhail V.; Kempe, Rhett
f-Element–Metal Bonding and the Use of the Bond Polarity To Build Molecular Intermetalloids
in Chemistry : a European Journal vol. 18 (2012) issue 43. - pp. 13566-13579
doi:10.1002/chem.201200783 ...

Zaheer, Muhammad; Schmalz, Thomas; Motz, Günter; Kempe, Rhett
Polymer derived non-oxide ceramics modified with late transition metals
in Chemical Society Reviews vol. 41 (2012) issue 15. - pp. 5102-5116
doi:10.1039/C2CS15326B ...

Dulle, Jana; Nemeth, Silke; Skorb, Ekaterina V.; Irrgang, Torsten; Senker, Jürgen; Kempe, Rhett; Fery, Andreas; Andreeva, Daria V.
Sonochemical Activation of AlNi Hydrogenation Catalyst
in Advanced Functional Materials vol. 22 (2012) issue 15. - pp. 3128-3135
doi:10.1002/adfm.201200437 ...

Zaheer, Muhammad; Keenan, Caroline D.; Hermannsdörfer, Justus; Roessler, Ernest; Motz, Günter; Senker, Jürgen; Kempe, Rhett
Robust Microporous Monoliths with Integrated Catalytically Active Metal Sites Investigated by Hyperpolarized 129Xe NMR
in Chemistry of Materials vol. 24 (2012) issue 20. - pp. 3952-3963
doi:10.1021/cm302379b ...

2011

Butovskii, Mikhail V.; Tok, Oleg L.; Bezugly, Viktor; Wagner, Frank R.; Kempe, Rhett
Molecular lanthanoid-transition-metal cluster through C-H bond activation by polar metal-metal bonds
in Angewandte Chemie International Edition vol. 50 (2011) issue 33. - pp. 7695-7698
doi:10.1002/anie.201102363 ...

Hermannsdörfer, Justus; Kempe, Rhett
Selective Palladium-Loaded MIL-101 Catalysts
in Chemistry : a European Journal vol. 17 (2011) issue 29. - pp. 8071-8077
doi:10.1002/chem.201101004 ...

Kutlescha, Kathrin; Venkanna, Gopaladasu T.; Kempe, Rhett
The potassium hydride mediated trimerization of imines
in Chemical Communications vol. 47 (2011) issue 14. - pp. 4183-4185
doi:10.1039/C0CC04565A ...

Irrgang, Torsten; Friedrich, Denise; Kempe, Rhett
Highly enantioselective amido iridium catalysts for the hydrogenation of simple ketones
in Angewandte Chemie International Edition vol. 50 (2011) issue 9. - pp. 2183-2186
doi:10.1002/anie.201004665 ...

Noor, Awal; Sobgwi Tamne, Emmanuel; Qayyum, Sadaf; Bauer, Tobias; Kempe, Rhett
Cycloaddition Reactions of a Chromium–Chromium Quintuple Bond
in Chemistry : a European Journal vol. 17 (2011) issue 25. - pp. 6900-6903
doi:10.1002/chem.201100841 ...

Lyubov, Dmitrii M.; Döring, Christian; Ketkov, Sergej Yu.; Kempe, Rhett; Trifonov, Alexander A.
Selective Protonation of the Y[BOND]C Bond in Trinuclear Yttrium Alkyl–Hydrido Clusters and Formation of the Cationic Polyhydrido Core
in Chemistry : a European Journal vol. 17 (2011) issue 14. - pp. 3824-3826
doi:10.1002/chem.201003616 ...

Schwarzmaier, Christoph; Noor, Awal; Glatz, Germund; Zabel, Manfred; Timoshkin, Alexey Y.; Cossairt, Brandi M.; Cummins, Christopher C.; Kempe, Rhett; Scheer, Manfred
Formation of cyclo-E42- Units (E4=P4, As4, AsP3) by a Complex with a Cr[BOND]Cr Quintuple Bond
in Angewandte Chemie International Edition vol. 50 (2011) issue 32. - pp. 7283-7286
doi:10.1002/anie.201102361 ...

2010

Butovskii, Mikhail V.; Döring, Christian; Bezugly, Viktor; Wagner, Frank R.; Grin, Yuri; Kempe, Rhett
Molecules containing rare-earth atoms solely bonded by transition metals
in Nature Chemistry vol. 2 (2010) issue 9. - pp. 741-744
doi:10.1038/nchem.718 ...

Michlik, Stefan; Kempe, Rhett
New Iridium Catalysts for the Efficient Alkylation of Anilines by Alcohols under Mild Conditions
in Chemistry : a European Journal vol. 16 (2010) issue 44. - pp. 13193-13198
doi:10.1002/chem.201001871 ...

Döring, Christian; Dietel, Anna-Maria; Butovskii, Mikhail V.; Bezugly, Viktor; Wagner, Frank R.; Kempe, Rhett
Molecular [Yb(TM)2] Intermetalloids (TM=Ru, Re)
in Chemistry : a European Journal vol. 16 (2010) issue 35. - pp. 10679-10683
doi:10.1002/chem.201001310 ...

Blank, Benoît; Kempe, Rhett
Catalytic Alkylation of Methyl-N-Heteroaromatics with Alcohols
in Journal of the American Chemical Society vol. 132 (2010) issue 3. - pp. 924-925
doi:10.1021/ja9095413 ...

Glatz, Germund; Schmalz, Thomas; Kraus, Tobias; Haarmann, Frank; Motz, Günter; Kempe, Rhett
Copper-Containing SiCN Precursor Ceramics (Cu@SiCN) as Selective Hydrocarbon Oxidation Catalysts Using Air as an Oxidant
in Chemistry : a European Journal vol. 16 (2010) issue 14. - pp. 4231-4238
doi:10.1002/chem.200902836 ...

2009

Blank, Benoît; Michlik, Stefan; Kempe, Rhett
Synthesis of Selectively Mono-N-Arylated Aliphatic Diamines via Iridium-Catalyzed Amine Alkylation
in Advanced Synthesis & Catalysis vol. 351 (2009) issue 17. - pp. 2903-2911
doi:10.1002/adsc.200900548 ...

Noor, Awal; Glatz, Germund; Müller, R.; Kaupp, Martin; Demeshko, Serhiy; Kempe, Rhett
Carboalumination of a chromium-chromium quintuple bond
in Nature Chemistry vol. 1 (2009) issue 4. - pp. 322-325
doi:10.1038/nchem.255 ...

Blank, Benoît; Michlik, Stefan; Kempe, Rhett
Selective iridium-catalyzed alkylation of (hetero)aromatic amines and diamines with alcohols under mild reaction conditions
in Chemistry : a European Journal vol. 15 (2009) issue 15. - pp. 3790-3799
doi:10.1002/chem.200802318 ...

Wagner, Frank R.; Noor, Awal; Kempe, Rhett
Ultrashort metal–metal distances and extreme bond orders
in Nature Chemistry vol. 1 (2009) issue 7. - pp. 529-536
doi:10.1038/nchem.359 ...

2008

Butovskii, M. V.; Tok, Oleg L.; Wagner, Frank R.; Kempe, Rhett
Bismetallocenes : lanthanoid-transition-metal bonds through alkane elimination
in Angewandte Chemie International Edition vol. 47 (2008) issue 34. - pp. 6469-6472
doi:10.1002/anie.200800407 ...

Proch, Sebastian; Hermannsdörfer, Justus; Kempe, Rhett; Kern, Christoph; Jess, Andreas; Seyfarth, Lena; Senker, Jürgen
Pt@MOF-177 : Synthesis, Room-Temperature Hydrogen Storage and Oxidation Catalysis
in Chemistry : a European Journal vol. 14 (2008) issue 27. - pp. 8204-8212
doi:10.1002/chem.200801043 ...

Noor, Awal; Wagner, Frank R.; Kempe, Rhett
Metal-metal distances at the limit : a coordination compound with an ultrashort chromium-chromium bond
in Angewandte Chemie International Edition vol. 47 (2008) issue 38. - pp. 7246-7249
doi:10.1002/anie.200801160 ...

Schrinner, Marc C.; Proch, Sebastian; Mei, Yu; Kempe, Rhett; Miyajima, Nobuyoshi; Ballauff, Matthias
Stable Bimetallic Gold–Platinum Nanoparticles Immobilized on Spherical Polyelectrolyte Brushes : Synthesis, Characterization, and Application for the Oxidation of Alcohols
in Advanced Materials vol. 20 (2008) issue 10. - pp. 1928-1933
doi:10.1002/adma.200702421 ...

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